Recycling

Optimizing Recycled Polymers for High-Performance Applications

Navigating Stabilization Challenges in Recycling Streams

The use of recycled polymers in manufacturing, particularly for lower-value items like trash bags, has become common but presents challenges in achieving a truly self-sustaining circular economy. Addressing the degradation mechanisms during the processing and use of plastic parts is crucial for developing high-performance materials.

Before delving into new stabilization strategies for recycled polymers, it’s essential to grasp the stabilization of conventional resins such as PE, PET, and PVC. In-depth guides on antioxidants and UV stabilizers provide comprehensive insights into these foundational aspects.

Assessing Recycled Plastic Quality

The quality and challenges associated with recycled polymers vary based on the recycling stream. From leftovers and scraps to post-consumer waste, each stream poses unique considerations for stabilization. Pre-consumer and post-industrial waste offer better quality, while post-consumer waste presents significant challenges due to variability in composition and thermal history.

Recycled materials undergo thermal stress in their previous life, necessitating the addition of antioxidants and heat stabilizers. Unlike optimal concentrations in virgin materials, recycled polymers may lack sufficient stabilizers for new thermal cycles. Applying stabilizers similar to those used for virgin materials can mitigate degradation and preserve physical and mechanical properties.

Specialized Grades for Recycled Plastics

Using grades designed explicitly for recycled plastics, such as BASF’s IrgaCycle™ series, can enhance performance by neutralizing contaminants and impurities. This proves particularly beneficial for post-consumer recycled plastics prone to impurity-related degradation.

Outdoor applications demand protection against sun-induced degradation. Leveraging chemistries akin to those used for virgin materials safeguards against issues like brittleness, yellowing, and loss of color or gloss. Grades tailored for recycled resins provide additional defense against sun degradation, neutralizing residues that may promote degradation.

Mitigating Excess Stabilizer Usage

Uncertainty in recyclate composition and batch-to-batch variability raises the risk of excess stabilizer usage. This could lead to migration and leaching during processing. Carbon black in dark-colored recycled polymers contributes to UV resistance, offering a potential positive aspect amid challenges.

Optimizing recycled polymers for high-performance applications demands a nuanced approach. By understanding the unique characteristics of various recycling streams and employing targeted stabilization strategies, plastics engineers can enhance the circularity and sustainability of their products. Explore specialized grades, adhere to UV protection principles, and carefully manage stabilizer usage to unlock the full potential of recycled plastics in manufacturing.

By Plastics Engineering | January 17, 2024

Recent Posts

  • Vinyl

Enzyme-Activated PVC: Redefining Vinyl’s End-of-Life Pathway

Hyphyn introduces enzyme-driven PVC biodegradation, achieving over 90% breakdown under ASTM D5511; however, real-world landfill…

2 days ago
  • PFAS

PFAS Contamination Tests the Limits of UK Policy

PFAS contamination is now systemic across the UK. Engineers and regulators must decide between incremental…

3 days ago
  • Design

The Gecko Effect: How Shape-Memory Polymers Redefine Smart Adhesion

Shape-memory polymers enable strong, reversible adhesion inspired by nature, advancing smart adhesives for robotics and…

4 days ago
  • Recycling

Upcycling PTFE Products with Sodium Metal

A new sodium-based method upcycles PTFE into fluorochemicals at room temperature, reducing PFAS risk and…

5 days ago
  • Industry

Polymer Sorbents for Critical Minerals

Engineered polymers extract rare-earth ions from contaminated leachates, reducing acid consumption, cycle time, and solvent…

6 days ago
  • Energy Generation

Plastic Waste to Hydrogen—and Lubricant Additives—for H₂ Engines

Turning mixed plastic waste into hydrogen fuel and carbon nanomaterials for H₂ engines and advanced…

7 days ago